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Thermo Fisher Scientific Inc
  
Material Safety Data Sheet
Ethyl bromopyruvate
Section 1 - Chemical Product and Company Identification
MSDS Name: Ethyl bromopyruvate
Catalog Numbers: 11815-0000, 11815-0050, 11815-0250, SB00905DA, SB00905EA, SB00905EE
Synonyms:
Company Identification: Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
Company Identification: (USA)Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
For information in the US, call: 800-ACROS-01
For information in Europe, call: +32 14 57 52 11
Emergency Number, Europe: +32 14 57 52 99
Emergency Number US:201-796-7100
CHEMTREC Phone Number, US: 800-424-9300
CHEMTREC Phone Number, Europe: 703-527-3887
Section 2 - Composition, Information on Ingredients
CAS# Chemical Name: % EINECS#
70-23-5 Ethyl bromopyruvate 80-85% 200-729-6
Hazard Symbols: C
  
Risk Phrases: 34
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Causes burns.
Potential Health Effects
Eye: Causes eye burns. Lachrymator (substance which increases the flow of tears).
Skin: Causes skin burns.
Ingestion: Causes gastrointestinal tract burns.
Inhalation: Causes chemical burns to the respiratory tract.
Chronic:
Section 4 - First Aid Measures
Eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Skin: Get medical aid immediately. Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion: Do not induce vomiting. Get medical aid immediately.
Inhalation: Get medical aid immediately. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Notes to Physician: Treat symptomatically and supportively.
Section 5 - Fire Fighting Measures
General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media: Use foam, dry chemical, or carbon dioxide.
Section 6 - Accidental Release Measures
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks: Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container.
Section 7 - Handling and Storage
Handling: Do not breathe dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use only in a chemical fume hood.
Storage: Keep away from sources of ignition. Store in a tightly closed container. Store in a dry area. Corrosives area. Keep refrigerated. (Store below 4°C/39°F.)
Section 8 - Exposure Controls, Personal Protection
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits
CAS# 70-23-5:
Personal Protective Equipment
Eyes: Wear chemical splash goggles.
Skin: Wear appropriate protective gloves to prevent skin exposure.
Clothing: Wear appropriate protective clothing to prevent skin exposure.
Respirators: Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.
Section 9 - Physical and Chemical Properties
Physical State: Clear liquid
Color: yellow
Odor: Not available
pH: Not available
Vapor Pressure: Not available
Viscosity: Not available
Boiling Point: 98 - 100 deg C @10mmHg
Freezing/Melting Point: Not available
Autoignition Temperature: Not available
Flash Point: 98 deg C ( 208.40 deg F)
Explosion Limits: Lower:Not available
Explosion Limits: Upper:Not available
Decomposition Temperature: Not available
Solubility in water: Not available
Specific Gravity/Density: 1.550
Molecular Formula: C5H7BrO3
Molecular Weight: 195.01
Section 10 - Stability and Reactivity
Chemical Stability: Stable under normal temperatures and pressures.
Conditions to Avoid: Incompatible materials.
Incompatibilities with Other Materials Incompatible materials, reducing agents, acids, bases.
Hazardous Decomposition Products Carbon monoxide, carbon dioxide, hydrogen bromide.
Hazardous Polymerization Will not occur.
Section 11 - Toxicological Information
RTECS#: CAS# 70-23-5: None listed
LD50/LC50: RTECS: Not available.
Carcinogenicity: Ethyl bromopyruvate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
Other: The toxicological properties have not been fully investigated.
Section 12 - Ecological Information
Not available
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
IATA IMO RID/ADR
Shipping Name: CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.* CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S. CORROSIVE LIQUID, ACIDIC, ORGANIC, N.O.S.
Hazard Class: 8 8 8
UN Number: 3265 3265 3265
Packing Group: III III III
Section 15 - Regulatory Information
European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: C
Risk Phrases:
R 34 Causes burns.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S 36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
S 45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
WGK (Water Danger/Protection)
CAS# 70-23-5: Not available
Canada
CAS# 70-23-5 is listed on Canada's NDSL List
US Federal
TSCA
CAS# 70-23-5 is listed on the TSCA Inventory.
Section 16 - Other Information
MSDS Creation Date: 7/16/1996
Revision #1 Date 10/19/2004
Revisions were made in Sections: General revision.

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages.
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