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| Cross Reference | |  | |
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Section 1 - Chemical Product and Company Identification |
| MSDS Name: |
Diallylamine, 97%
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| Catalog Numbers: |
11204-0000, 11204-0010, 11204-0050, 11204-2500
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| Synonyms: |
Di-2-propenylamine
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| Company Identification:
| Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
| | Company Identification: (USA) | Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
| | For information in the US, call:
| 800-ACROS-01 |
| For information in Europe, call: | +32 14 57 52 11 |
| Emergency Number, Europe: | +32 14 57 52 99 |
| Emergency Number US: | 201-796-7100 |
| CHEMTREC Phone Number, US:
| 800-424-9300 |
| CHEMTREC Phone Number, Europe:
| 703-527-3887 |
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Section 2 - Composition, Information on Ingredients
|
| CAS# |
Chemical Name: |
% |
EINECS# |
| 124-02-7 |
Diallylamine |
97% |
204-671-2 |
| Hazard Symbols: |
T F
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| 
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| Risk Phrases: |
11 20/22 24 34
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
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Highly flammable. Harmful by inhalation and if swallowed. Toxic in
contact with skin. Causes burns.
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Potential Health Effects |
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Eye: |
Causes eye burns. Lachrymator (substance which increases the flow
of tears).
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Skin: |
Causes skin burns. Toxic in contact with skin. Substance is readily
absorbed through the skin.
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Ingestion: |
Harmful if swallowed. Causes gastrointestinal tract burns. May cause
burning sensations, coughing, wheezing, laryngitis, shortness of
breath and headache.
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Inhalation: |
Harmful if inhaled. Causes chemical burns to the respiratory tract.
Inhalation may be fatal as a result of spasm, inflammation, edema of
the larynx and bronchi, chemical pneumonitis and pulmonary edema. May
cause burning sensation, coughing, wheezing, laryngitis, shortness of
breath, headache, nausea, and vomiting.
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Chronic: |
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Section 4 - First Aid Measures |
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Eyes: |
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
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Skin: |
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
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Ingestion: |
Do not induce vomiting. Get medical aid immediately. Wash mouth out
with water.
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Inhalation: |
Remove from exposure and move to fresh air immediately. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical aid.
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Notes to Physician: |
Treat symptomatically and supportively.
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Section 5 - Fire Fighting Measures |
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General Information: |
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors can travel to a source of ignition and flash
back. Will burn if involved in a fire. Containers may explode in the
heat of a fire. Flammable liquid and vapor.
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Extinguishing Media: |
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide.
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Section 6 - Accidental Release Measures |
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General Information: |
Use proper personal protective equipment as indicated in Section 8.
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Spills/Leaks: |
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
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Section 7 - Handling and Storage |
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Handling: |
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
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Storage: |
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container.
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Section 8 - Exposure Controls, Personal Protection |
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Engineering Controls:
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Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate general or
local explosion-proof ventilation to keep airborne levels to
acceptable levels.
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Exposure Limits |
| CAS# 124-02-7: |
| Personal Protective Equipment
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Eyes: |
Wear chemical splash goggles.
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Skin: |
Wear appropriate protective gloves to prevent skin
exposure.
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Clothing: |
Wear appropriate protective clothing to prevent skin
exposure.
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Respirators: |
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties |
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Physical State: | Clear liquid |
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Color: | clear colorless to yellow
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Odor: | Not available |
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pH: | 11.5(9.7g/l aq.sol.) |
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Vapor Pressure: | 18 mm Hg @20 deg C |
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Viscosity: | Not available |
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Boiling Point: | 110 - 112 deg C @ 760 mmHg |
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Freezing/Melting Point: | -88 deg C ( -126.40°F) |
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Autoignition Temperature: | Not available |
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Flash Point: | 7 deg C ( 44.60 deg F) |
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Explosion Limits: Lower: | 2.2 Vol% |
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Explosion Limits: Upper: | 22 Vol% |
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Decomposition Temperature: | Not available |
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Solubility in water: | 90 g/l in water (20°C) |
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Specific Gravity/Density: | 0.789 g/cm3 |
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Molecular Formula: | C6H11N |
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Molecular Weight: | 97.16 |
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Section 10 - Stability and Reactivity |
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Chemical Stability: |
Stable.
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Conditions to Avoid: |
Incompatible materials, ignition sources.
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Incompatibilities with Other Materials |
Strong oxidizing agents, acids, acid chlorides, carbon dioxide, acid
anhydrides.
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Hazardous Decomposition Products |
Nitrogen oxides, carbon monoxide, carbon dioxide.
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Hazardous Polymerization |
Will not occur.
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Section 11 - Toxicological Information |
| RTECS#: |
CAS# 124-02-7: UC6650000
| | LD50/LC50: |
RTECS:
CAS# 124-02-7: Inhalation, rat: LC50 = 795
ppm/8H;
Oral, mouse: LD50 = 355 mg/kg;
Oral, rat: LD50 = 578
mg/kg;
Skin, rabbit: LD50 = 280 uL/kg;
.
Other:
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Carcinogenicity: |
Diallylamine -
Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
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Other: |
See actual entry in RTECS for complete information. The toxicological
properties have not been fully investigated.
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Section 12 - Ecological Information |
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Ecotoxicity: |
Not available
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Section 13 - Disposal Considerations |
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Dispose of in a manner consistent with federal, state, and local regulations.
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Section 14 - Transport Information |
|
| IATA
| IMO
| RID/ADR
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| Shipping Name:
|
DIALLYLAMINE
|
DIALLYLAMINE
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DIALLYLAMINE
|
| Hazard Class:
| 3 (6.1)
| 3 (6.1)
| 3 (6.1)
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| UN Number:
| 2359
| 2359
| 2359
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| Packing Group:
| II
| II
| II
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Section 15 - Regulatory Information |
| European/International Regulations |
| European Labeling in Accordance with EC Directives |
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Hazard Symbols: T F
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Risk Phrases: |
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R 11 Highly flammable.
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R 20/22 Harmful by inhalation and if swallowed.
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R 24 Toxic in contact with skin.
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R 34 Causes burns.
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| Safety Phrases: |
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S 16 Keep away from sources of ignition - No
smoking.
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S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
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S 28A After contact with skin, wash immediately with
plenty of water.
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S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
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S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
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| WGK (Water Danger/Protection) |
| CAS# 124-02-7: Not available |
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| Canada |
| CAS# 124-02-7 is listed on Canada's DSL List |
| |
| US Federal |
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TSCA |
| CAS# 124-02-7 is listed on the TSCA Inventory. |
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Section 16 - Other Information |
| MSDS Creation Date: |
7/16/1996 |
| Revision #1 Date |
10/03/2000 |
| Revisions were made in Sections: |
General revision. |
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