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| Cross Reference | |  | |
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Section 1 - Chemical Product and Company Identification |
| MSDS Name: |
Allyl bromide, stabilized
|
| Catalog Numbers: |
10290-0000, 10290-0025, 10290-0050, 10290-0100, 10290-2500, 10290-5000
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| Synonyms: |
3-Bromopropene
|
| Company Identification:
| Acros Organics BVBA
Janssen Pharmaceuticalaan 3a
2440 Geel, Belgium
| | Company Identification: (USA) | Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
| | For information in the US, call:
| 800-ACROS-01 |
| For information in Europe, call: | +32 14 57 52 11 |
| Emergency Number, Europe: | +32 14 57 52 99 |
| Emergency Number US: | 201-796-7100 |
| CHEMTREC Phone Number, US:
| 800-424-9300 |
| CHEMTREC Phone Number, Europe:
| 703-527-3887 |
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Section 2 - Composition, Information on Ingredients
|
| CAS# |
Chemical Name: |
% |
EINECS# |
Hazard Symbols: |
Risk Phrases: |
| 106-95-6 |
Allyl bromide |
99% |
203-446-6 |
|
|
Text for R-phrases: see Section 16
| Hazard Symbols: |
T F N
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| 
| 
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| Risk Phrases: |
11 23/25 34 50
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Section 3 - Hazards Identification
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EMERGENCY OVERVIEW
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Highly flammable. Toxic by inhalation and if swallowed. Causes
burns. Very toxic to aquatic organisms.
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Potential Health Effects |
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Eye: |
Causes eye burns. Lachrymator (substance which increases the flow
of tears). Causes redness and pain.
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Skin: |
Causes skin burns. Causes redness and pain. May be harmful if
absorbed through the skin.
| |
Ingestion: |
May cause gastrointestinal irritation with nausea, vomiting and
diarrhea. Causes gastrointestinal tract burns. Toxic if swallowed.
| |
Inhalation: |
Causes chemical burns to the respiratory tract. Toxic if inhaled.
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Chronic: |
May cause liver and kidney damage.
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Section 4 - First Aid Measures |
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Eyes: |
Immediately flush eyes with plenty of water for at least 15 minutes,
occasionally lifting the upper and lower eyelids. Get medical aid
immediately.
| |
Skin: |
Get medical aid immediately. Immediately flush skin with plenty of
water for at least 15 minutes while removing contaminated clothing
and shoes.
| |
Ingestion: |
Get medical aid immediately. Wash mouth out with water.
| |
Inhalation: |
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen.
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Notes to Physician: |
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Section 5 - Fire Fighting Measures |
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General Information: |
As in any fire, wear a self-contained breathing apparatus in
pressure-demand, MSHA/NIOSH (approved or equivalent), and full
protective gear. Vapors may form an explosive mixture with air.
Vapors can travel to a source of ignition and flash back. Containers
may explode in the heat of a fire. Flammable liquid and vapor.
| |
Extinguishing Media: |
Use water spray to cool fire-exposed containers. Use foam, dry
chemical, or carbon dioxide. Water may be ineffective.
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Section 6 - Accidental Release Measures |
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General Information: |
Use proper personal protective equipment as indicated in Section 8.
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Spills/Leaks: |
Absorb spill with inert material (e.g. vermiculite, sand or earth),
then place in suitable container. Remove all sources of ignition.
Use a spark-proof tool.
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Section 7 - Handling and Storage |
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Handling: |
Use spark-proof tools and explosion proof equipment. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on
clothing. Use only in a chemical fume hood.
| |
Storage: |
Keep away from sources of ignition. Store in a cool, dry place.
Store in a tightly closed container. Flammables-area.
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Section 8 - Exposure Controls, Personal Protection |
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Engineering Controls:
| |
Facilities storing or utilizing this material should be equipped
with an eyewash facility and a safety shower. Use adequate
ventilation to keep airborne concentrations low.
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Exposure Limits |
| CAS# 75-56-9:
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United Kingdom, WEL - TWA: 5 ppm TWA; 12 mg/m3 TWA
United Kingdom, WEL - STEL: 15 ppm STEL; 36 mg/m3 STEL
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United States OSHA: 100 ppm TWA; 240 mg/m3 TWA
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Belgium - TWA: 20 ppm VLE; 49 mg/m3 VLE
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France - VME: 20 ppm VME; 50 mg/m3 VME
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Germany: 2.5 ppm TWA; 6 mg/m3 TWA
Germany: skin notation
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Malaysia: 20 ppm TWA; 48 mg/m3 TWA
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Netherlands: 2.5 ppm MAC; 6 mg/m3 MAC
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Spain: 5 ppm VLA-ED; 12 mg/m3 VLA-ED
| |
| CAS# 106-95-6: |
| Personal Protective Equipment
| |
Eyes: |
Wear chemical splash goggles.
| |
Skin: |
Wear appropriate protective gloves to prevent skin
exposure.
| |
Clothing: |
Wear appropriate protective clothing to prevent skin
exposure.
| |
Respirators: |
Follow the OSHA respirator regulations found in 29
CFR 1910.134 or European Standard EN 149. Use a
NIOSH/MSHA or European Standard EN 149 approved
respirator if exposure limits are exceeded or if
irritation or other symptoms are experienced.
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Section 9 - Physical and Chemical Properties |
| |
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Physical State: | Clear liquid |
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Color: | Not available
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Odor: | unpleasant odor - stench
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pH: | Not available |
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Vapor Pressure: | 147mbar @20 deg C |
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Viscosity: | Not available |
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Boiling Point: | 70 - 71 deg C @760mmHg |
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Freezing/Melting Point: | -119 deg C ( -182.20°F) |
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Autoignition Temperature: | 295 deg C ( 563.00 deg F) |
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Flash Point: | -1 deg C ( 30.20 deg F) |
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Explosion Limits: Lower: | 4.4 Vol % |
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Explosion Limits: Upper: | 7.3 Vol % |
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Decomposition Temperature: | Not available |
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Solubility in water: | Insoluble |
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Specific Gravity/Density: | 1.390 |
|
Molecular Formula: | C3H5Br |
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Molecular Weight: | 120.98 |
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Section 10 - Stability and Reactivity |
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Chemical Stability: |
Stable under normal temperatures and pressures. Light sensitive.
| |
Conditions to Avoid: |
Incompatible materials, light, ignition sources.
| |
Incompatibilities with Other Materials |
Strong oxidizing agents, strong bases.
| |
Hazardous Decomposition Products |
Carbon monoxide, carbon dioxide, hydrogen bromide.
| |
Hazardous Polymerization |
May occur.
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Section 11 - Toxicological Information |
| RTECS#: |
CAS# 75-56-9: TZ2975000
CAS# 106-95-6: UC7090000
| | LD50/LC50: |
RTECS:
CAS# 75-56-9: Draize test, rabbit, eye: 20 mg
Severe;
Draize test, rabbit, eye: 20 mg/24H Moderate;
Draize
test, rabbit, skin: 50 mg/6M Severe;
Inhalation, mouse: LC50 =
1740 ppm/4H;
Inhalation, rat: LC50 = 4000 ppm/4H;
Oral,
mouse: LD50 = 440 mg/kg;
Oral, rat: LD50 = 380 mg/kg;
Skin,
rabbit: LD50 = 1500 uL/kg;
.
RTECS:
CAS# 106-95-6: Inhalation, mouse: LC50 = 4110
mg/m3/2H;
Inhalation, rat: LC50 = 10 gm/m3/30M;
Inhalation,
rat: LC50 = 10000 mg/m3/2H;
Oral, rat: LD50 = 120 mg/kg;
.
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Carcinogenicity: |
Propylene oxide -
ACGIH: A3 - Confirmed animal carcinogen with unknown relevance to humans
California: carcinogen, initial date 10/1/88
NTP: Suspect carcinogen
IARC: Group 2B carcinogen
Allyl bromide -
Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65.
| |
Other: |
See actual entry in RTECS for complete information. The toxicological
properties have not been fully investigated.
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Section 12 - Ecological Information |
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Ecotoxicity: |
Fish: LC50: <0.8 mg/l; 24H; .
Daphnia: EC50: <0.8 mg/l; 48H; .
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Section 13 - Disposal Considerations |
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Dispose of in a manner consistent with federal, state, and local regulations.
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Section 14 - Transport Information |
|
| IATA
| IMO
| RID/ADR
|
| Shipping Name:
|
ALLYL BROMIDE(forbidden to ship via passenger air)
|
ALLYL BROMIDE
|
ALLYL BROMIDE
|
| Hazard Class:
| 3 (6.1)
| 3 (6.1)
| 3 (6.1)
|
| UN Number:
| 1099
| 1099
| 1099
|
| Packing Group:
| I
| I
| I
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| USA RQ: CAS# 75-56-9: 100 lb final RQ; 45.4 kg final RQ
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| Marine Pollutant
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Section 15 - Regulatory Information |
| European/International Regulations |
| European Labeling in Accordance with EC Directives |
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Hazard Symbols: T F N
|
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Risk Phrases: |
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R 11 Highly flammable.
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R 23/25 Toxic by inhalation and if swallowed.
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R 34 Causes burns.
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R 50 Very toxic to aquatic organisms.
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| Safety Phrases: |
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S 16 Keep away from sources of ignition - No
smoking.
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S 36/37/39 Wear suitable protective clothing, gloves
and eye/face protection.
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S 45 In case of accident or if you feel unwell, seek
medical advice immediately (show the label where
possible).
|
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S 61 Avoid release to the environment. Refer to
special instructions/safety data sheets.
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| WGK (Water Danger/Protection) |
| CAS# 75-56-9: 2 |
| CAS# 106-95-6: Not available |
|
| Canada |
| CAS# 75-56-9 is listed on Canada's DSL List |
| CAS# 106-95-6 is listed on Canada's DSL List |
| |
| US Federal |
|
TSCA |
| CAS# 75-56-9 is listed on the TSCA Inventory. |
| CAS# 106-95-6 is listed on the TSCA Inventory. |
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Section 16 - Other Information |
| Text for R-phrases from Section 2 |
| MSDS Creation Date: |
7/16/1996 |
| Revision #2 Date |
1/25/2008 |
| Revisions were made in Sections: |
1, 2, 3, 9, 10, 14 |
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